Abubuwan da aka samo asali na alkyl polyglycoside.

Don bayyana kaddarorin abubuwan da suka samo asali na alkyl polyglycoside, an yi rikodin tashin hankali / karkatar da hankali da mahimmancin micelle (cmc) da ƙimar tashin hankali saman tudu sama da cmc daga gare su. An binciko tashin hankali na tsaka-tsakin a kan abubuwa biyu na samfur: octyl dodecanol da decane-an bincika su azaman ƙarin sigogi. Ana nuna ƙimar cmc da aka samu daga waɗannan maƙallan a hoto na 8. bayanan da suka dace don C₁₂ alkyl monoglycoside da kuma a_{C 12/14}An haɗa alkyl polyglycoside don kwatanta. Ana iya ganin cewa alkyl polyglycoside glycerol ethers da carbonates suna da ƙimar cmc mafi girma fiye da alkyl polyglycosides na tsayin sarkar daidai yayin da ƙimar cmc na monobutyl ethers sun ɗan yi ƙasa da na alkyl polyglycosides.

An gudanar da ma'aunin tashin hankali na tsaka-tsakin fuska tare da ɗigowar tensiometer na Kri.iss. Don daidaita yanayin aiki, an yi ma'aunin a cikin ruwa mai wuya (270 ppm Ca: Mg = 5: ll a cikin ƙwayar surfactant na 0.15 g / l kuma a SO Hoto 9 yana nuna kwatancen tashin hankali na interfacial na C.₁₂Abubuwan da aka samo asali na alkyl polyglycoside akan octyl dodecanol. The C₁₂mono[1]butyl ether yana da mafi girman tashin hankali na tsaka-tsaki kuma saboda haka mafi ƙarancin ayyukan tsaka-tsakin yayin da C.₁₂monoglycerol ether yana da mahimmanci a matakin C₁₂polybutyl ether. The C₁₂alkyl polyglycoside an haɗa don kwatanta ta'allaka ne a matakin ƙarshe na biyu na alkyl polyglycoside da aka ambata. Gabaɗaya, ƙimar tashin hankali na tsaka-tsaki a kan octyl dodecanol suna da girma sosai. Wannan yana nufin cewa, don aikace-aikace masu amfani, yana da mahimmanci don tabbatar da cewa gaurayawan surfactant da aka yi amfani da su suna da haɗin kai ga mai.

Sakamakon gwajin kumfa kamar Hoto 10. An auna halayen kumfa na alkyl polyglycoside monoglycerol ethers da monocarbonates ta hanyar kwatanta da C.₁₂alkyl polyglycoside don ƙimar taurin ruwa guda biyu idan babu ƙasa mai kitse. An gudanar da ma'auni daidai da DIN 53 902. C₁₀kuma C₁₂alkyl polyglycoside monoglycerol ethers ya samar da ƙarar kumfa mafi girma fiye da C₁₂alkyl polyglycoside. Kwanciyar kumfa yana da girma sosai a yanayin C₁₂monoglycerol ether fiye da na C₁₀ wanda aka samu a 16°dH. The C₁₄Alkyl polyglycoside monoglycerol ether ba ya kwatanta da C₁₀kuma C₁₂ Abubuwan da aka samo a cikin ikon kumfa kuma, gabaɗaya, ƙima sun fi C₁₂alkyl polyglycoside. Mono-carbonates tare da tsayin sarkar alkyl n na 8 da 12 an bambanta su da ƙananan kumfa, kamar yadda za a sa ran na abin da aka samu na hydrophobic alkyl polyglycoside.