Ta hanyar polyfunctionality na carbohydrates, acid catalyzed Fischer halayen suna da sharadi don samar da cakuda oligomer wanda a cikin matsakaici fiye da ɗaya naúrar glycation yana haɗe zuwa microsphere barasa. Matsakaicin adadin raka'a na glycose da ke da alaƙa da ƙungiyar barasa an kwatanta shi azaman (matsakaici) digiri na polymerization (DPI. Figure2 yana nuna rarrabawa ga alkyl polyglycoside tare da DP = 1.3. A cikin wannan cakuda, ƙaddamarwa na mutum oligomers (mono-, di-, tri-, -, glycoside) ya fi mayar dogara ne akan rabo na glucose zuwa barasa (DPI) polymerization yana dogara ne akan rabo na glucose zuwa barasa a cikin yanayin da aka yi. Tsarin sunadarai na jiki da aikace-aikace na alkyl polyglycosides A cikin rarraba ma'auni, DP- na tsawon sarkar da aka ba da shi ya dace da ainihin samfurin Properties, irin su polarity, solubility, da dai sauransu Rarraba Flory yana kwatanta alkyl polyglycosides a matsayin cakuda oligomers da aka rarraba ta kididdiga.
Abubuwan da ke cikin nau'in nau'in mutum ɗaya a cikin cakuda oligomer yana raguwa tare da ƙara darajar polymerization. Rarraba oligomer da aka samu ta wannan tsarin lissafin ya yi daidai da sakamakon nazari (duba Babi na 3). A cikin sauƙi, matsakaicin matakin polymerization (DP) na gaurayawan alkyl polyglycoside za a iya ƙididdige su daga mole kashi pi na nau'in oligomeric "i" a cikin cakuda glycoside (Hoto 2)